Perfil (CV) del personal docente investigador

Fernández Álvarez, Francisco José
Departamento: Departamento de Química Inorgánica
Área: Química Inorgánica
Centro: Facultad de Ciencias

Research Institute: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Grupo: CATÁLISIS HOMOGÉNEA POR COMPUESTOS ORGANOMETÁLICOS

Códigos UNESCO
  • Compuestos organometálicos
Categoría profesional: Prof. Titular Univ.

Cargos
  • Profesor Secretario del Departamento de Química Inorgánica
Correo electrónico: paco@unizar.es
ORCID: 0000-0002-0497-1969

Líneas de investigación
  • Catálisis
  • Química organometálica
 
         

Artículos

  • Cascarosa Salillas, María Esther; Pozuelo Muñoz, Jorge; Jiménez, Mercedes; Fenández Álvarez, Francisco J. Analysis of the mental model about the atom concept in Spanish 15- to 18- years old students. EDUCACION QUIMICA. 2022

  • García-Orduña P.; Fernández I.; Oro L.A.; Fernández-Alvarez F.J. Origin of the Ir-Si bond shortening in Ir-NSiN complexes. DALTON TRANSACTIONS. 2021

  • Fernández-Alvarez, F.J.; Oro, L.A. Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide. TOPICS IN ORGANOMETALLIC CHEMISTRY. 2021

  • Iglesias M.; Fernández-Alvarez F.J. Advances in nonprecious metal homogeneously catalyzed formic acid dehydrogenation. CATALYSTS. 2021

  • Fernández-Alvarez, F.J.; Oro, L.A. Correction to: Chapters (Top Organomet Chem). TOPICS IN ORGANOMETALLIC CHEMISTRY. 2021

  • Guzmán, J.; Bernal, A.M.; García-Orduña, P.; Lahoz, F.J.; Polo, V.; Fernández-Alvarez, F.J. 2-Pyridone-stabilized iridium silylene/silyl complexes: Structure and QTAIM analysis. DALTON TRANSACTIONS. 2020

  • Guzmán, Jefferson; García-Orduña, Pilar; Lahoz, Fernando J.; Fernández-Alvarez, Francisco J. Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO2 with hydrosilanes. RSC ADVANCES. 2020

  • Guzmán, J.; Bernal, A.M.; García-Orduña, P.; Lahoz, F.J.; Oro, L.A.; Fernández-Alvarez, F.J. Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe 2 Ph catalyzed by iridium complexes. DALTON TRANSACTIONS. 2019

  • Fernández-Alvarez, Francisco J.; Polo, Víctor; García-Orduña, Pilar; Lahoz, Fernando J.; Pérez-Torrente, Jesús J.; Oro, Luis A.; Lalrempuia, Ralte. Synthesis and reactivity at the Ir- Me Tpm platform: from ¿ 1 -: N coordination to ¿ 3 -N-based organometallic chemistry. DALTON TRANSACTIONS. 2019

  • Iglesias, Manuel; Fernández-Álvarez, Francisco J.; Oro, Luis A. Non-classical hydrosilane mediated reductions promoted by transition metal complexes. COORDINATION CHEMISTRY REVIEWS. 2019

  • Ojeda-Amador, A.I.; Munarriz, J.; Alamán-Valtierra, P.; Polo, V.; Puerta-Oteo, R.; Jiménez, M.V.; Fernández-Alvarez, F.J.; Pérez-Torrente, J.J. Mechanistic Insights on the Functionalization of CO2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate-Functionalized Bis-NHC Catalyst. CHEMCATCHEM. 2019

  • Guzmán, Jefferson; Torguet, Adrían; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A.; Fernández-Alvarez, Francisco J. Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2019

  • Guzman, J.; Garcia-Orduna, P.; Polo, V.; Lahoz, F.J.; Oro, L.A.; Fernandez-Alvarez, F.J. Ir- catalyzed selective reduction of CO2 to the methoxy or formate level with HSiMe.OSiMe3)2. CATALYSIS SCIENCE AND TECHNOLOGY. 2019

  • Julián, A.; Garcés, K.; Lalrempuia, R.; Jaseer, E.A.; García-Orduña, P.; Fernández-Alvarez, F.J.; Lahoz, F.J.; Oro, L.A. Reactivity of Ir–NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids. CHEMCATCHEM. 2018

  • Fernández Álvarez, Francisco José. Conciencia Química y CO2. CONCIENCIAS.DIGITAL. 2018

  • Fernandez-Alvarez, F.J.; Oro, L.A. Homogeneous Catalytic Reduction of CO2 with Silicon-Hydrides, State of the Art. CHEMCATCHEM. 2018

  • Cascarosa Salillas, María Esther; Fernández-Álvarez, Francisco J.; Santiago, Francisco J. Un estudio del uso de modelos moleculares en la didáctica del enlace covalente en bachillerato. REIDOCREA-REVISTA EECTRONICA DE INVESTIGACION Y DOCENCIA CREATIVA. 2018

  • Julián, A.; Polo, V.; Fernández-Alvarez, F.J.; Oro, L.A. Iridium-NSiN catalyzed formation of silylphosphinecarboxylates from the reaction of CO2 with P(SiMe3)R2 (R = Ph, Cy). CATALYSIS SCIENCE AND TECHNOLOGY. 2017

  • Fernández-Alvarez, F.J.; Lalrempuia, R.; Oro, L.A. Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis. COORDINATION CHEMISTRY REVIEWS. 2017

  • Fernández-Álvarez, J.; Díaz García, Amanda; González Robles, Vicente Alberto; Baños, R.; García Palacios, Azucena; Botella Arbona, Cristina. Dropping out of a transdiagnostic online intervention: a qualitative analysis of client's experiences. INTERNET INTERVENTIONS-THE APPLICATION OF INFORMATION TECHNOLOGY IN MENTAL AND BEHAVIOURAL HEALTH. 2017

  • Julián, A.; Guzmán, J.; Jaseer, E.A.; Fernández-Alvarez, F.J.; Royo, R.; Polo, V.; García-Orduña, P.; Lahoz, F.J.; Oro, L.A. Mechanistic Insights on the Reduction of CO2 to Silylformates Catalyzed by Ir-NSiN Species. CHEMISTRY - A EUROPEAN JOURNAL. 2017

  • Julián, Alejandro; Jaseer, E. A.; Garcés, Karin; Fernández-Alvarez, Francisco José; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A. Tuning the activity and selectivity of iridium-NSiN catalyzed CO2 hydrosilylation processes. CATALYSIS SCIENCE AND TECHNOLOGY. 2016

  • Garcés, K.;Lalrempuia, R.;Polo, V.;Fernández-Alvarez, F. J.;García-Orduña, P.;Lahoz, F. J.;Pérez-Torrente, J. J.;Oro, L. A. Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers. CHEMISTRY - A EUROPEAN JOURNAL. 2016

  • Aliaga-Lavrijsen, Mélanie; Iglesias, Manuel; Cebollada, Andrea; Garcés, Karin; García, Nestor; Sanz Miguel, Pablo J.; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis- N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups. ORGANOMETALLICS. 2015

  • Jaseer,E. A.; Akhtar,M. N.; Osman,M.; Al-Shammari,A.; Oladipo,H. B.; Garcés,K.; Fernández-Alvarez,F. J.; Al-Khattaf,S.; Oro,L. A. Solvent-free iridium-catalyzed CO2 hydrosilylation: Experiments and kinetic modeling. CATALYSIS SCIENCE AND TECHNOLOGY. 2015

  • Lázaro,G.; Polo,V.; Fernández-Alvarez,F. J.; García-Orduña,P.; Lahoz,F. J.; Iglesias,M.; Pérez-Torrente,J. J.; Oro,L. A. Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts. CHEMSUSCHEM. 2015

  • Lázaro,G.; Fernández-Alvarez,F. J.; Munárriz,J.; Polo,V.; Iglesias,M.; Pérez-Torrente,J. J.; Oro,L. A. Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: Its role in the catalytic hydrosilylation of ketones. CATALYSIS SCIENCE AND TECHNOLOGY. 2015

  • Iglesias,M.; Aliaga-Lavrijsen,M.; Miguel,P. J. S.; Fernández-Alvarez,F. J.; Pérez-Torrente,J. J.; Oro,L. A. Preferential a -hydrosilylation of terminal alkynes by bis-N-heterocyclic carbene rhodium(III) catalysts. ADVANCED SYNTHESIS AND CATALYSIS. 2015

  • Garcés, K.; Fernández-Alvarez, F. J.; García-Orduña, P.; Lahoz, F. J.; Pérez-Torrente, J. J.; Oro, L. A. Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis. CHEMCATCHEM. 2015

  • Oladipo, H. B.; Jaseer, E. A.; Julián, A.; Fernández-Alvarez, F. J.; Al-Khattaf, S.; Oro, L. A. Effect of the CO2-pressure on the hydrosilylation of CO2 catalyzed by [Ir(NSiN)] species. JOURNAL OF CO2 UTILIZATION. 2015

  • Julian, Alejandro; Polo, Victor; Jaseer, E. A.; Fernandez-Alvarez, Francisco J.; Oro, Luis A.; Solvent-Free Iridium-Catalyzed Reactivity of CO2 with Secondary Amines and Hydrosilanes. CHEMCATCHEM. 2015

  • Iglesias, Manuel; Fernández-Alvarez, Francisco J.; Oro, Luis A. Outer-sphere ionic hydrosilylation catalysis. CHEMCATCHEM. 2014

  • Lázaro, Guillermo; Fernández-Alvarez, Francisco J.; Iglesias, Manuel; Horna, Cristina; Vispe, Eugenio; Sancho, Rodrigo; Lahoz, Fernando J.; Iglesias, Marta; Pérez-Torrente, Jesús J.; Oro, Luís A. Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation. CATALYSIS SCIENCE AND TECHNOLOGY. 2014

  • Fernández-Alvarez, F. J.; Aitani, A. M.; Oro, L. A. Homogeneous catalytic reduction of CO2 with hydrosilanes. CATALYSIS SCIENCE AND TECHNOLOGY. 2014

  • Garcés, K.; Fernández-Alvarez, F. J.; Polo, V.; Lalrempuia, R.; Pérez-Torrente, J. J.; Oro, L. A. Iridium-catalyzed hydrogen production from hydrosilanes and water. CHEMCATCHEM. 2014

  • Fernández Álvarez, Francisco José. Hidrosilanos como Fuente de Hidrógeno en Procesos Catalíticos Homogéneos para la Reducción de CO2. REVISTA DE LA ACADEMIA DE CIENCIAS EXACTAS, FÍSICO-QUÍMICAS Y NATURALES DE ZARAGOZA. 2013

  • Lázaro, G.; Iglesias, M.; Fernández-Alvarez, F. J.; Sanz Miguel, P. J.; Pérez-Torrente, J. J.; Oro, L. A. Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis. CHEMCATCHEM. 2013

  • Fernández-Alvarez, Francisco J; Iglesias, Manuel; Oro, Luis A; Polo, Victor. CO2 Activation and Catalysis Driven by Iridium Complexes. CHEMCATCHEM. 2013

  • Iglesias, M.; Sanz Miguel, P. J.; Polo, V.; Fernández-Alvarez, F. J.; Pérez-Torrente, J. J.; Oro, L. A. An Alternative Mechanistic Paradigm for the ß-Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle. CHEMISTRY - A EUROPEAN JOURNAL. 2013

  • Lalrempuia, R.; Iglesias, M.; Polo, V.; Sanz Miguel, P.J.; Fernández-Alvarez, F.J.; Pérez-Torrente, J.J.; Oro, L.A. Effective Fixation of CO2 by Iridium-Catalysed Hydrosilylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2012

  • Iglesias, Manuel; Pérez-Nicolás, María; Sanz Miguel, Pablo J.; Polo Ortiz, Victor; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. . A synthon for a 14-electron Ir( III) species: catalyst for highly selective b -( Z ) hydrosilylation of terminal alkynes. CHEMICAL COMMUNICATIONS. 2012

  • Esteruelas, M. A.;Fernandez-Alvarez, F. J.;Lopez, A. M.;Mora, M. ;Oñate, E. Borinium cations as (sigma)-B-H ligands in osmium complexes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2010

  • Esteruelas, M. A.; Fernandez-Alvarez, F.; Olivan, M.; Oñate, E. NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand. ORGANOMETALLICS. 2009

  • Esteruelas, M. A.;Fernandez-Alvarez,F.;Oñate,E. NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism. ORGANOMETALLICS. 2008

  • Esteruelas, M. A.;Fernandez-Alvarez,F.;Oñate,E. Osmium and Ruthenium Complexes Containing an N-Heterocyclic Carbene Ligand Derived from Benzo[h]Quinoline. ORGANOMETALLICS. 2007

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Olivan,M.;Onate,E. C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-Vinylpyridine acetylene couplings. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Onate,E. Stabilization of NH tautomers of quinolines by osmium and ruthenium. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Lopez,A. M.;Onate,E.;Ruiz-Sanchez,P. Iridium(I), iridium(III), and iridium(V) complexes containing the (2-methoxyethyl)cyclopentadienyl ligand. ORGANOMETALLICS. 2006

  • Esteruelas, M. A.;Fernandez, F. J.;Lopez, A. M.;Oñate, E. Stabilization of a Chelate Tautomer of Phenylacetylide. ORGANOMETALLICS. 2003

  • Fernández, Francisco J.; Venkatesan, Koushik; Blacque, Olivier; Alfonso, Monserrat; Schmalle, Helmut, H.; Berke, Heinz. Generation and Coupling of [Mn(dmpe)2(C[TRIPLE BOND]CR)(C[TRIPLE BOND]C)]. Radicals Producing Redox-Active C4-Bridged Rigid-Rod Complexes. CHEMISTRY - A EUROPEAN JOURNAL. 2003

  • Venkatesan, Koushik; Fernández, Francisco J.; Blacque, Olivier; Fox, Thomas; Alfonso, Montserrat; Schmalle, Helmut W.; Berke, Heinz A facile and novel route to unprecedented manganese C4 cumulenic complexes. CHEMICAL COMMUNICATIONS. 2003

  • Fernández, Francisco J.; Alfonso, Montserrat ; Schmalle, Helmut W.; Berke, Heinz. Utilization of Redox and Acid/Base Chemistry for the Deprotection of a Mn(dmpe)2(CtCSiMe3)2 Complex. ORGANOMETALLICS. 2001

  • Fernández, Francisco J.; Galakhov, Mikhail V.; Royo, Pascual. Reactivity of vinyl and alkynyl zirconium complexes with the di-ansa-[1,1',2,2'-bis(dimethylsilanediyl) dicyclopentadienyl] ligand. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2000

Comunicaciones

  • Fernández, Francisco J.; Blacque, Olivier; Alfonso, Montserrat; Berke, Heinz. A facile and new type of route to the redox-active rigid-rod complex [{Mn(dmpe)2(C·CH)}2(m-C4)][PF6] via Mn–C2· radical coupling. CHEMICAL COMMUNICATIONS. 2001

Capítulos

  • Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide. Fernández Álvarez, Francisco José. TOPICS IN ORGANOMETALLIC CHEMISTRY. 2020

  • Bond Activation and Catalysis. Fernández Álvarez, Francisco José. COMPREHENSIVE INORGANIC CHEMISTRY II: FROM ELEMENTS TO APPLICATIONS. 2013



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