Perfil (CV) del personal docente investigador

Fernández Álvarez, Francisco José
Departamento: Departamento de Química Inorgánica
Área: Química Inorgánica
Centro: Facultad de Ciencias

Research Institute: INSTITUTO DE SÍNTESIS QUÍMICA Y CATÁLISIS HOMOGÉNEA (ISQCH)
Grupo: E42_23R: Catálisis Homogénea por Compuestos Organometálicos

Códigos UNESCO
  • Compuestos organometálicos
Categoría profesional: Prof. Titular Univ.

Cargos
  • Profesor Secretario del Departamento de Química Inorgánica
Correo electrónico: paco@unizar.es
ORCID: 0000-0002-0497-1969

Líneas de investigación
  • Catálisis
  • Química organometálica

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Artículos

  • Gómez-España, Alejandra; García-Orduña, Pilar; Lahoz, Fernando J.; Fernández, Israel; Fernández-Álvarez, Francisco J. Rhodium Complexes with a Pyridine-2-yloxy-silyl-Based N,Si-Ligand: Bonding Situation and Activity as Alkene Hydrogenation Catalysts. ORGANOMETALLICS. 2024. DOI: 10.1021/acs.organomet.3c00498

  • Gómez-España, Alejandra; López-Morales, Jorge L.; Español-Sanchez, Belinda; García-Orduña, Pilar; Lahoz, Fernando J.; Iglesias, Manuel; Fernández-Alvarez, Francisco J. Iridium-(K2-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance. DALTON TRANSACTIONS. 2023. DOI: 10.1039/d3dt00744h

  • Guzmán, Jefferson; Urriolabeitia, Asier; Padilla, Marina; García-Orduña, Pilar; Polo, Víctor; Fernández-Alvarez, Francisco J. Mechanism insights into the Iridium(III)- and B(C6F5)3-Catalyzed reduction of CO2 to the Formaldehyde Level with Tertiary Silanes. INORGANIC CHEMISTRY. 2022. DOI: 10.1021/acs.inorgchem.2c03330

  • Guzmán, Jefferson; Urriolabeitia, Asier; Polo, Víctor; Fernández-Buenestado, Marta; Iglesias, Manuel; Fernández-Álvarez, Francisco J. Dehydrogenation of formic acid using iridium-NSi species as catalyst precursors. DALTON TRANSACTIONS. 2022. DOI: 10.1039/d1dt04335h

  • Gómez España, Alejandra; García Orduña, Pilar; Guzmán, Jefferson; Fernández, Israel; Fernández Álvarez, Francisco J. Synthesis and characterization of Ir-(k2-NSi) Species Active toward the solventless hydrolysis of HSiMe(OSiMe3)2. INORGANIC CHEMISTRY. 2022. DOI: 10.1021/acs.inorgchem.2c01973

  • Cascarosa Salillas, María Esther; Pozuelo Muñoz, Jorge; Jiménez, Mercedes; Fenández Álvarez, Francisco J. Analysis of the mental model about the atom concept in Spanish 15- to 18- years old students. EDUCACION QUIMICA. 2022. DOI: 10.22201/fq.18708404e.2022.2.79895

  • García-Orduña Pilar; Fernández Israel; Oro Luis A.; Fernández-Alvarez Francisco J. Origin of the Ir-Si bond shortening in Ir-NSiN complexes. DALTON TRANSACTIONS. 2021. DOI: 10.1039/d1dt00473e

  • Fernández-Alvarez, F.J.; Oro, L.A. Correction to: Chapters (Top Organomet Chem). TOPICS IN ORGANOMETALLIC CHEMISTRY. 2021. DOI: 10.1007/3418_2020_73

  • Iglesias M.; Fernández-Alvarez F.J. Advances in nonprecious metal homogeneously catalyzed formic acid dehydrogenation. CATALYSTS. 2021. DOI: 10.3390/catal11111288

  • Guzmán, J.; Bernal, A.M.; García-Orduña, P.; Lahoz, F.J.; Polo, V.; Fernández-Alvarez, F.J. 2-Pyridone-stabilized iridium silylene/silyl complexes: Structure and QTAIM analysis. DALTON TRANSACTIONS. 2020. DOI: 10.1039/d0dt03326j

  • Fernández-Alvarez, Francisco J.; Oro, Luis A. Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide. TOPICS IN ORGANOMETALLIC CHEMISTRY. 2020. DOI: 10.1007/3418_2020_52

  • Guzmán, Jefferson; García-Orduña, Pilar; Lahoz, Fernando J.; Fernández-Alvarez, Francisco J. Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO2 with hydrosilanes. RSC ADVANCES. 2020. DOI: 10.1039/d0ra00204f

  • Iglesias, Manuel; Fernández-Álvarez, Francisco J.; Oro, Luis A. Non-classical hydrosilane mediated reductions promoted by transition metal complexes. COORDINATION CHEMISTRY REVIEWS. 2019. DOI: 10.1016/j.ccr.2019.02.003

  • Fernández-Alvarez, Francisco J.; Polo, Víctor; García-Orduña, Pilar; Lahoz, Fernando J.; Pérez-Torrente, Jesús J.; Oro, Luis A.; Lalrempuia, Ralte. Synthesis and reactivity at the Ir-MeTpm platform: from k1-N coordination to k3-N-based organometallic chemistry. DALTON TRANSACTIONS. 2019. DOI: 10.1039/c9dt00703b

  • Guzmán, Jefferson; Bernal, Ana M.; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A.; Fernández-Alvarez, Francisco J. Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe2Ph catalyzed by iridium complexes. DALTON TRANSACTIONS. 2019. DOI: 10.1039/c8dt05070h

  • Guzmán, Jefferson; Torguet, Adrían; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A.; Fernández-Alvarez, Francisco J. Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2019. DOI: 10.1016/j.jorganchem.2019.06.010

  • Ojeda-Amador, A.I.; Munarriz, J.; Alamán-Valtierra, P.; Polo, V.; Puerta-Oteo, R.; Jiménez, M.V.; Fernández-Alvarez, F.J.; Pérez-Torrente, J.J. Mechanistic insights on the functionalization of CO2 with amines and hydrosilanes catalyzed by a Zwitterionic iridium carboxylate-functionalized bis-NHC catalyst. CHEMCATCHEM. 2019. DOI: 10.1002/cctc.201901687

  • Guzman, Jefferson; Garcia-Orduna, Pilar; Polo, Víctor; Lahoz, Fernand J.; Oro, Luis A.; Fernandez-Alvarez, Francisco J. Ir-catalyzed selective reduction of CO2 to the methoxy or formate level with HSiMe(OSiMe3)2. CATALYSIS SCIENCE AND TECHNOLOGY. 2019. DOI: 10.1039/c8cy02353k

  • Fernández Álvarez, Francisco José. Conciencia Química y CO2. CONCIENCIAS.DIGITAL. 2018

  • Fernandez-Alvarez, Francisco J.; Oro, Luis A. Homogeneous Catalytic Reduction of CO2 with Silicon-Hydrides, State of the Art. CHEMCATCHEM. 2018. DOI: 10.1002/cctc.201800699

  • Julián, A.; Garcés, K.; Lalrempuia, R.; Jaseer, E.A.; García-Orduña, P.; Fernández-Alvarez, F.J.; Lahoz, F.J.; Oro, L.A. Reactivity of Ir–NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids. CHEMCATCHEM. 2018. DOI: 10.1002/cctc.201701488

  • Cascarosa Salillas, María Esther; Fernández-Álvarez, Francisco J.; Santiago, Francisco J. Un estudio del uso de modelos moleculares en la didáctica del enlace covalente en bachillerato.. REVISTA ELECTRÓNICA DE INVESTIGACIÓN Y DOCENCIA CREATIVA. 2018

  • Fernández-Alvarez, F.J.; Lalrempuia, R.; Oro, L.A. Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis. COORDINATION CHEMISTRY REVIEWS. 2017. DOI: 10.1016/j.ccr.2017.04.011

  • Fernández-Álvarez, J.; Díaz García, Amanda; González Robles, Vicente Alberto; Baños, R.; García Palacios, Azucena; Botella Arbona, Cristina. Dropping out of a transdiagnostic online intervention: a qualitative analysis of client's experiences. INTERNET INTERVENTIONS-THE APPLICATION OF INFORMATION TECHNOLOGY IN MENTAL AND BEHAVIOURAL HEALTH. 2017. DOI: 10.1016/j.invent.2017.09.001

  • Julián, A.; Guzmán, J.; Jaseer, E.A.; Fernández-Alvarez, F.J.; Royo, R.; Polo, V.; García-Orduña, P.; Lahoz, F.J.; Oro, L.A. Mechanistic Insights on the Reduction of CO2 to Silylformates Catalyzed by Ir-NSiN Species. CHEMISTRY - A EUROPEAN JOURNAL. 2017. DOI: 10.1002/chem.201702246

  • Julián, A.; Polo, V.; Fernández-Alvarez, F.J.; Oro, L.A. Iridium-NSiN catalyzed formation of silylphosphinecarboxylates from the reaction of CO2 with P(SiMe3)R2 (R = Ph, Cy). CATALYSIS SCIENCE AND TECHNOLOGY. 2017. DOI: 10.1039/c7cy00115k

  • Garcés, K.;Lalrempuia, R.;Polo, V.;Fernández-Alvarez, F. J.;García-Orduña, P.;Lahoz, F. J.;Pérez-Torrente, J. J.;Oro, L. A. Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers. CHEMISTRY - A EUROPEAN JOURNAL. 2016. DOI: 10.1002/chem.201602760

  • Julián, Alejandro; Jaseer, E. A.; Garcés, Karin; Fernández-Alvarez, Francisco José; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A. Tuning the activity and selectivity of iridium-NSiN catalyzed CO2 hydrosilylation processes. CATALYSIS SCIENCE AND TECHNOLOGY. 2016. DOI: 10.1039/C5CY02139A

  • Aliaga-Lavrijsen, Mélanie; Iglesias, Manuel; Cebollada, Andrea; Garcés, Karin; García, Nestor; Sanz Miguel, Pablo J.; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis- N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups. ORGANOMETALLICS. 2015. DOI: 10.1021/om5011726

  • Lázaro,G.; Polo,V.; Fernández-Alvarez,F. J.; García-Orduña,P.; Lahoz,F. J.; Iglesias,M.; Pérez-Torrente,J. J.; Oro,L. A. Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts. CHEMSUSCHEM. 2015. DOI: 10.1002/cssc.201403036

  • Julian, Alejandro; Polo, Victor; Jaseer, E. A.; Fernandez-Alvarez, Francisco J.; Oro, Luis A.; Solvent-Free Iridium-Catalyzed Reactivity of CO2 with Secondary Amines and Hydrosilanes. CHEMCATCHEM. 2015. DOI: 10.1002/cctc.201500651

  • Oladipo, H. B.; Jaseer, E. A.; Julián, A.; Fernández-Alvarez, F. J.; Al-Khattaf, S.; Oro, L. A. Effect of the CO2-pressure on the hydrosilylation of CO2 catalyzed by [Ir(NSiN)] species. JOURNAL OF CO2 UTILIZATION. 2015. DOI: 10.1016/j.jcou.2015.10.001

  • Lázaro,Guillermo; Fernández-Alvarez, Francisco J.; Munárriz, Julen; Polo, Víctor; Iglesias, Manuel; Pérez-Torrente, Jesús J.; Oro, Luis A. Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: Its role in the catalytic hydrosilylation of ketones. CATALYSIS SCIENCE AND TECHNOLOGY. 2015. DOI: 10.1039/c4cy01556h

  • Garcés, K.; Fernández-Alvarez, F. J.; García-Orduña, P.; Lahoz, F. J.; Pérez-Torrente, J. J.; Oro, L. A. Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis. CHEMCATCHEM. 2015. DOI: 10.1002/cctc.201500508

  • Jaseer,E. A.; Akhtar,M. N.; Osman,M.; Al-Shammari,A.; Oladipo,H. B.; Garcés,K.; Fernández-Alvarez,F. J.; Al-Khattaf,S.; Oro,L. A. Solvent-free iridium-catalyzed CO2 hydrosilylation: Experiments and kinetic modeling. CATALYSIS SCIENCE AND TECHNOLOGY. 2015. DOI: 10.1039/c4cy00815d

  • Iglesias,M.; Aliaga-Lavrijsen,M.; Miguel,P. J. S.; Fernández-Alvarez,F. J.; Pérez-Torrente,J. J.; Oro,L. A. Preferential a -hydrosilylation of terminal alkynes by bis-N-heterocyclic carbene rhodium(III) catalysts. ADVANCED SYNTHESIS AND CATALYSIS. 2015. DOI: 10.1002/adsc.201400673

  • Lázaro, Guillermo; Fernández-Alvarez, Francisco J.; Iglesias, Manuel; Horna, Cristina; Vispe, Eugenio; Sancho, Rodrigo; Lahoz, Fernando J.; Iglesias, Marta; Pérez-Torrente, Jesús J.; Oro, Luís A. Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation. CATALYSIS SCIENCE AND TECHNOLOGY. 2014. DOI: 10.1039/c3cy00598d

  • Garcés, K.; Fernández-Alvarez, F. J.; Polo, V.; Lalrempuia, R.; Pérez-Torrente, J. J.; Oro, L. A. Iridium-catalyzed hydrogen production from hydrosilanes and water. CHEMCATCHEM. 2014. DOI: 10.1002/cctc.201301107

  • Iglesias, Manuel; Fernández-Alvarez, Francisco J.; Oro, Luis A. Outer-sphere ionic hydrosilylation catalysis. CHEMCATCHEM. 2014. DOI: 10.1002/cctc.201402355

  • Fernández-Alvarez, F. J.; Aitani, A. M.; Oro, L. A. Homogeneous catalytic reduction of CO2 with hydrosilanes. CATALYSIS SCIENCE AND TECHNOLOGY. 2014. DOI: 10.1039/c3cy00948c

  • Fernández Álvarez, Francisco José. Hidrosilanos como Fuente de Hidrógeno en Procesos Catalíticos Homogéneos para la Reducción de CO2. REVISTA DE LA ACADEMIA DE CIENCIAS EXACTAS, FÍSICO-QUÍMICAS Y NATURALES DE ZARAGOZA. 2013

  • Iglesias, M.; Sanz Miguel, P. J.; Polo, V.; Fernández-Alvarez, F. J.; Pérez-Torrente, J. J.; Oro, L. A. An Alternative Mechanistic Paradigm for the ß-Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle. CHEMISTRY - A EUROPEAN JOURNAL. 2013. DOI: 10.1002/chem.201303063

  • Lázaro, G.; Iglesias, M.; Fernández-Alvarez, F. J.; Sanz Miguel, P. J.; Pérez-Torrente, J. J.; Oro, L. A. Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis. CHEMCATCHEM. 2013. DOI: 10.1002/cctc.201200309

  • Fernández-Alvarez, Francisco J; Iglesias, Manuel; Oro, Luis A; Polo, Victor. CO2 Activation and Catalysis Driven by Iridium Complexes. CHEMCATCHEM. 2013. DOI: 10.1002/cctc.201300559

  • Iglesias, Manuel; Pérez-Nicolás, María; Sanz Miguel, Pablo J.; Polo Ortiz, Victor; Fernández-Alvarez, Francisco J.; Pérez-Torrente, Jesús J.; Oro, Luis A. . A synthon for a 14-electron Ir( III) species: catalyst for highly selective b -( Z ) hydrosilylation of terminal alkynes. CHEMICAL COMMUNICATIONS. 2012. DOI: 10.1039/C2CC34931K

  • Lalrempuia, R.; Iglesias, M.; Polo, V.; Sanz Miguel, P.J.; Fernández-Alvarez, F.J.; Pérez-Torrente, J.J.; Oro, L.A. Effective Fixation of CO2 by Iridium-Catalysed Hydrosilylation. ANGEWANDTE CHEMIE (INTERNATIONAL ED.). 2012. DOI: 10.1002/ange.201206165

  • Esteruelas, M. A.;Fernandez-Alvarez, F. J.;Lopez, A. M.;Mora, M. ;Oñate, E. Borinium cations as (sigma)-B-H ligands in osmium complexes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2010. DOI: 10.1021/ja101806x

  • Esteruelas, M. A.; Fernandez-Alvarez, F.; Olivan, M.; Oñate, E. NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand. ORGANOMETALLICS. 2009. DOI: 10.1021/om8011954

  • Esteruelas, M. A.;Fernandez-Alvarez,F.;Oñate,E. NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism. ORGANOMETALLICS. 2008

  • Esteruelas, M. A.;Fernandez-Alvarez,F.;Oñate,E. Osmium and Ruthenium Complexes Containing an N-Heterocyclic Carbene Ligand Derived from Benzo[h]Quinoline. ORGANOMETALLICS. 2007

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Onate,E. Stabilization of NH tautomers of quinolines by osmium and ruthenium. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Olivan,M.;Onate,E. C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-Vinylpyridine acetylene couplings. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006

  • Esteruelas,M. A.;Fernandez-Alvarez,F. J.;Lopez,A. M.;Onate,E.;Ruiz-Sanchez,P. Iridium(I), iridium(III), and iridium(V) complexes containing the (2-methoxyethyl)cyclopentadienyl ligand. ORGANOMETALLICS. 2006

  • Fernández, Francisco J.; Venkatesan, Koushik; Blacque, Olivier; Alfonso, Monserrat; Schmalle, Helmut, H.; Berke, Heinz. Generation and Coupling of [Mn(dmpe)2(C[TRIPLE BOND]CR)(C[TRIPLE BOND]C)]. Radicals Producing Redox-Active C4-Bridged Rigid-Rod Complexes. CHEMISTRY - A EUROPEAN JOURNAL. 2003. DOI: 10.1002/chem.200305254

  • Venkatesan, Koushik; Fernández, Francisco J.; Blacque, Olivier; Fox, Thomas; Alfonso, Montserrat; Schmalle, Helmut W.; Berke, Heinz A facile and novel route to unprecedented manganese C4 cumulenic complexes. CHEMICAL COMMUNICATIONS. 2003. DOI: 10.1039/B304882A

  • Esteruelas, M. A.;Fernandez, F. J.;Lopez, A. M.;Oñate, E. Stabilization of a Chelate Tautomer of Phenylacetylide. ORGANOMETALLICS. 2003

  • Fernández, Francisco J.; Alfonso, Montserrat ; Schmalle, Helmut W.; Berke, Heinz. Utilization of Redox and Acid/Base Chemistry for the Deprotection of a Mn(dmpe)2(CtCSiMe3)2 Complex. ORGANOMETALLICS. 2001. DOI: 10.1021/om010172k

  • Fernández, Francisco J.; Galakhov, Mikhail V.; Royo, Pascual. Reactivity of vinyl and alkynyl zirconium complexes with the di-ansa-[1,1',2,2'-bis(dimethylsilanediyl) dicyclopentadienyl] ligand. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2000. DOI: 10.1016/S0022-328X(99)00633-6

Comunicaciones

  • Fernández, Francisco J.; Blacque, Olivier; Alfonso, Montserrat; Berke, Heinz. A facile and new type of route to the redox-active rigid-rod complex [{Mn(dmpe)2(C·CH)}2(m-C4)][PF6] via Mn–C2· radical coupling. CHEMICAL COMMUNICATIONS. 2001. DOI: 10.1039/b102396a

Capítulos

  • Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide. Fernández Álvarez, Francisco José. TOPICS IN ORGANOMETALLIC CHEMISTRY. 2020

  • Bond Activation and Catalysis. Fernández Álvarez, Francisco José. COMPREHENSIVE INORGANIC CHEMISTRY II: FROM ELEMENTS TO APPLICATIONS. 2013



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